Preheat the oven to 350 degrees Fahrenheit. Spray an 8-inch round cake pan with cooking spray. Line bottom of sprayed pan with parchment paper, then spray top of parchment paper with cooking spray one more time.
Spread White Honey on bottom of cake pan, carefully making sure it reaches as far to the sides as possible without moving the parchment paper. Place orange wheels atop honey in bottom of cake pan. Set aside.
Next, make the batter. In a small mixing bowl, whisk together the flour, baking powder, baking soda and salt. In a separate, medium mixing bowl, combine the sugar, eggs, yogurt, orange juice, orange zest and vanilla. Using a hand mixer, mix until these ingredients are combined, then mix in the dry ingredients.
Once all ingredients are incorporated, pour batter into prepared cake pan. Place in 350 degree oven for 50-60 minutes, or until a cake tester inserted into the center comes out clean. Let cool on a wire rack for 10-15 minutes, then invert onto a cake plate to finish cooling.
To make the whipped cream, combine heavy whipping cream, vanilla and bourbon in a stand mixer fitted with the whisk attachment. Mix at medium-high speed for at least 5 minutes, or until the mixture resembles whipped cream. Serve alongside slices of cake.